Skip to ContentSkip to Navigation
Over ons Praktische zaken Waar vindt u ons prof. dr. R. (Ronald) Hage

Research interests

The research of Prof Ronald Hage is focusing on developing new iron and manganese oxidation and bleach catalysts that activate hydrogen peroxide or dioxygen for selective oxidations. This work includes studies on elucidations of mechanisms using various spectroscopy and electrochemical methods, in collaboration with Prof. Wesley Browne.  Identification of intermediate active species of the oxidation reactions helps us to understand better the conditions of optimal use of the catalysts. These investigations are related to the application testing at Catexel, where similar catalysts are developed for use in industry. Using hydrogen peroxide and a catalyst can lead to the replacement of much more harmful oxidants.
A relatively new area is the activation of sodium chlorite to form chlorine dioxide in situ using an iron catalyst which is studied using UV-vis and Raman spectroscopy. Mechanistic studies are in progress to understand which iron-oxo species is involved in these reactions. Applications can be found in the areas of water treatment/antimicrobial benefits.

Publicaties

Activation of alkyl hydroperoxides by manganese complexes of tmtacn for initiation of radical polymerisation of alkenes

Reaction of (N4Py)Fe with H2O2 and the relevance of its Fe(IV)=O species during and after H2O2 disproportionation

Role of non-redox innocent ligand units in the oxidation of alcohols with H2O2 catalyzed by μ-oxido-diiron(III) bis-phenolato polypyridyl complexes

A Common Active Intermediate in the Oxidation of Alkenes, Alcohols and Alkanes with H2O2 and a Mn(II)/Pyridin-2-Carboxylato Catalyst

Reversible Deactivation of Manganese Catalysts in Alkene Oxidation and H2O2 Disproportionation

Toward Environmentally Benign Electrophilic Chlorinations: From Chloroperoxidase to Bioinspired Isoporphyrins

Mechanisms in manganese oxidation catalysis with 1,4,7-triazacyclononane based ligands

Lewis versus Brønsted Acid Activation of a Mn(IV) Catalyst for Alkene Oxidation

Manganese-Catalyzed Oxidation with Hydrogen Peroxide

Lees meer