Skip to ContentSkip to Navigation
About us Latest news News News articles

Orbital order and magnetoelectric coupling in manganites and jarosites

12 November 2010

PhD ceremony: Mr. A.J.C. Buurma, 11.00 uur, Academiegebouw, Broerstraat 5, Groningen

Thesis: Orbital order and magnetoelectric coupling in manganites and jarosites

Promotor(s): prof. T.T.M. Palstra

Faculty: Mathematics and Natural Sciences

 

Transition metal oxides show a wealth of physical properties that emanate from complex physics. Subtle lattice deformations can be reflected in distinct changes in physical properties. This thesis focuses on subtle interplay between the crystal lattice and physical properties. We aim to couple different physical phenomena to create multifunctional materials.

The first group of materials studied in this thesis encompasses orthorhombic NdMnO3. The Mn orbital degeneracy in manganates is lifted by a Jahn-Teller distortion to give a long range alternating pattern of short and long Mn-O bond lengths known as antiferrodistortive orbital order in the ab-plane. Both divalent Ca doping on the rare earth site as well as gallium doping on the octahedral Mn site suppresses orbital order in NdMnO3. X-ray diffraction experiments at elevated temperatures show that the first-order nature of the orbital order-disorder phase transition eventually gives way to a second-order phase transition. Magnetic measurements at low temperature show an enhancement in the ferromagnetic saturation moment with isovalent Ga-doping.

The second part of this thesis focuses on magneto-electric materials that allow the control of magnetic (electric) dipole moments by electric (magnetic) field. We investigate the possibility of a new magneto-electric coupling mechanism driven by symmetric superexchange interactions in iron jarosite. Finally, we compare the magnetic phase diagrams of the hexagonal manganates YbMnO3 and ErMnO3 as a function of temperature and applied magnetic field. We observe differences in the resistivity of the samples, which we attribute to different domain wall densities that result in different in critical fields.

Last modified:13 March 2020 01.15 a.m.
Share this Facebook LinkedIn
View this page in: Nederlands

More news

  • 01 April 2025

    NSC’s electoral reform plan may have unwanted consequences

    The new voting system, proposed by minister Uitermark, could jeopardize the fundamental principle of proportional representation, says Davide Grossi, Professor of Collective Decision Making and Computation at the University of Groningen

  • 01 April 2025

    ‘AiNed’ National Growth Fund grant for speeding adoption of AI at SMEs

    Professor Ming Cao receives an ‘AiNed’ Growth Fund grant of EUR 2.4 million for research that will contribute to faster adoption of AI at SMEs in the technical industry in the Netherlands.

  • 01 April 2025

    'Diversity leads to better science'

    In addition to her biological research on ageing, Hannah Dugdale also studies disparities relating to diversity in science. Thanks to the latter, she is one of the two 2024 laureates of the Athena Award, an NWO prize for successful and inspiring...